A frit is a type of ceramic glass. It is a combination of materials that, when melted together, are rendered insoluble and resistant to acid attack. They are, therefore, a means of introducing certain materials into a glaze which would otherwise be toxic. Frits can be used alone as low temperature glazes, e.g. raku and majolica, but generally they form the basis of a glaze recipe. Walker Ceramics offers a large range of frits and for those wishing to incorporate the frits in glaze calculations, molecular formulae are listed.
Lead Frits Glazes based on lead frits produce a shiny, durable finish and give brightness and clarity of colour when used in conjunction with oxides, stains, slips etc. While they can be used on all earthenware clays, they are particularly suitable for red clay.
Borax Frits Borax frits are often used in the production of earthenware glazes when a lead free glaze is required. Slight milkiness, especially at lower temperatures, may be evident over red clays, and the colour response with oxides, etc. is not usually so vivid as with lead frits.
Alkaline Frits Similar to borax frits, alkaline frits are noted for their high soda and potash content. The colour response from copper and manganese is turquoise and purple/brown respectively – typical of this type of frit. Alkaline frits have a high expansion rate which makes them a suitable base for crackle glazes.
The table below lists a detailed summary of the properties of the most commonly used frits.
Product Code Frit Number | Description | Use | CaO | Na2O | K2O | ZnO | PbO | Al2O3 | SiO2 | B2O3 | ZrO2 | Mol Wt | Soft Temp°C | Trans. Temp°C | COE Linear |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
DA4193 KMP4193 Replaces F938 | Clear, hard barium borosilicate lead free frit. E/W 1040-1100ºC | DISCONTINUED No Longer Available | 0.51 | 0.19 | 0.1 | 0.1 | 0.2 | 2.86 | 0.62 | BaO 0.1 | 308 | 653 | 590 | 64 | |
DA4110 KMP4110 Replaces F3110 & 1078 | Unleaded high alkali glaze frit. High expansion. 980-1080ºC | Copper blue and manganese purple glazes. For crackles. | 0.29 | 0.64 | 0.07 | 0.02 | 2.86 | 0.09 | 280 | 575 | 531 | 96 | |||
DA4124 KMP4124 Replaces F3124 | Lead free calciumborosilicate frit. E/W1040-1100ºC | 0.68 | 0.28 | 0.04 | 0.16 | 2.56 | 0.54 | 266 | 622 | 577 | 74 | ||||
DA4171 KMP4171 Replaces F3271 & 1057 | Lead free calcium borosilicate frit. E/W 1040-1100ºC | DISCONTINUED No Longer Available | 0.486 | 0.514 | 2.25 | 0.768 | 248 | 590 | 558 | 83 | |||||
DA9146 KMP9102 Replaces 3302-D & 1085 | Dense zircon white Lead free frit. E/W 1040-1100ºC | E/W whites and pastel coloured glazes. | 0.46 | 0.416 | MgO 0.064 | 0.058 | 0.173 | 4.04 | 0.836 | 0.427 | 431 | 628 | 573 | 59 | |
DA4064 KMP4064 /3531 Lead Bi-Silicate Replaces F4364 | Lead bisilicate frit. Standard low solubility. 950-1050ºC | 1 | 0.085 | 1.95 | 349 | 510 | 465 | 72 | |||||||
DA4108 Replaces F4508, F3134 & 1077 | Lead free calcium borosilicate frit. E/W 1040-1100ºC | DISCONTINUED No Longer Available Try 60% of 3134-2, 40% 4131 as a substitute blend. | 0.68 | 0.22 | 0.07 | 2 | 0.63 | 229 | 618 | 583 | 78 | ||||
DA4113 KMP4113 Replaces F4712 | Hard lead free clear borosilicate frit. E/W 1040-1100ºC | DISCONTINUED No Longer Available Try DA4131 | 0.6 | 0.27 | 0.13 | 0.35 | 3.5 | 0.63 | 353 | 652 | 586 | 69 | |||
DA4194 KMP4194 Replaces 5325P, 501E34, 5301 & 1012 | Lead free soft sodium borosilicate frit. High expansion 900-1060ºC | DISCONTINUED No Longer Available Try DA4110 | 0.14 | 0.66 | 0.2 | 0.29 | 2.96 | 0.67 | F2 0.40 | 329 | 559 | 518 | 93 | ||
DA3134 KMP3134-2 Mix 60:40 with 4131 to replace 4108 | Lead free calcium borosilicate frit. 980-1080ºC | 0.68 | 0.32 | 0.038 | 1.48 | 0.64 | 195 | 95 | |||||||
DA4131 KMP4131 | Lead free sodium borosilicate frit. 1050-1100ºC | General purpose for clear glazes. | 0.686 | 0.314 | 0.346 | 3.165 | 0.68 | 331 | 670 | 608 | 61 |